Heat a skillet over medium-high heat. Drizzle with olive oil.
Salt and pepper pork chops on both sides and place in skillet. Cook on both sides for about 3 minutes.
Top pork chops with peppers, onions, and tomatoes. Pour red wine vinegar over the vegetables. Cover and cook about 5 minutes more or until vegetables are tender and pork is cooked through.
Serve over rice.